1 00:00:00,240 --> 00:00:10,869 [Music] 2 00:00:15,829 --> 00:00:13,249 first of all I like to thank the 3 00:00:18,440 --> 00:00:15,839 opportunity to talk so this is my first 4 00:00:20,660 --> 00:00:18,450 time talking outside Brazil and maybe my 5 00:00:24,290 --> 00:00:20,670 English not very good but please forgive 6 00:00:26,630 --> 00:00:24,300 me um my name is Eleni I'm from Brazil 7 00:00:28,580 --> 00:00:26,640 and I'm finishing my master's right now 8 00:00:31,550 --> 00:00:28,590 and starting my PhD next month 9 00:00:34,430 --> 00:00:31,560 so this work I'm going to be showing you 10 00:00:37,009 --> 00:00:34,440 is my Master's work and it's about the 11 00:00:41,810 --> 00:00:37,019 information of molecules entitled 12 00:00:44,090 --> 00:00:41,820 atmosphere um first of all I like to 13 00:00:47,119 --> 00:00:44,100 start on telling you what's really 14 00:00:50,450 --> 00:00:47,129 interesting about Titan because many 15 00:00:53,149 --> 00:00:50,460 people don't know all the features so 16 00:00:58,009 --> 00:00:53,159 first of all we see the evidence of 17 00:01:01,759 --> 00:00:58,019 lakes really on the surface of the Moon 18 00:01:05,960 --> 00:01:01,769 just like the earth but um it they're 19 00:01:08,210 --> 00:01:05,970 basically formed by methane and organic 20 00:01:11,770 --> 00:01:08,220 molecules and you're gonna see that a 21 00:01:16,400 --> 00:01:11,780 little bit later as well we also see um 22 00:01:18,860 --> 00:01:16,410 volcanism just like the earth but some 23 00:01:21,890 --> 00:01:18,870 people believe there's a ocean of 24 00:01:25,640 --> 00:01:21,900 ammonia and water under the surface so 25 00:01:29,510 --> 00:01:25,650 maybe this is a way of um giving water 26 00:01:32,600 --> 00:01:29,520 to the surface after of the moon and my 27 00:01:36,530 --> 00:01:32,610 favorite part is right here that Titan 28 00:01:39,980 --> 00:01:36,540 is the only place in the solar system 29 00:01:43,370 --> 00:01:39,990 besides our planet that can is able to 30 00:01:45,410 --> 00:01:43,380 build complex and organic molecules so 31 00:01:48,050 --> 00:01:45,420 when I say complex I'm talking about 32 00:01:50,660 --> 00:01:48,060 molecules which are and which have at 33 00:01:52,730 --> 00:01:50,670 least six or more atoms and organic 34 00:01:55,490 --> 00:01:52,740 they're basically formed by carbon and 35 00:01:56,960 --> 00:01:55,500 hydrogen and we're gonna see some one 36 00:02:04,190 --> 00:01:56,970 because that's where all this nitrogen 37 00:02:08,389 --> 00:02:04,200 and oxygen so um a little bit um about 38 00:02:11,239 --> 00:02:08,399 the chemistry in Titan so just like he 39 00:02:13,509 --> 00:02:11,249 said before me we basically start 40 00:02:18,170 --> 00:02:13,519 everything with this two 41 00:02:21,649 --> 00:02:18,180 main molecules so these are nitrogen and 42 00:02:24,380 --> 00:02:21,659 methane so nitrogen is about 94 95 43 00:02:27,860 --> 00:02:24,390 percent in the atmosphere and methane is 44 00:02:30,289 --> 00:02:27,870 like basically the rest of it so this is 45 00:02:33,830 --> 00:02:30,299 where the chemistry all starts we have 46 00:02:36,970 --> 00:02:33,840 two main influences which are the solar 47 00:02:39,589 --> 00:02:36,980 radiation and basically in the u 48 00:02:43,460 --> 00:02:39,599 ultraviolet or extreme ultraviolet and 49 00:02:46,910 --> 00:02:43,470 we have another source of particles 50 00:02:50,479 --> 00:02:46,920 especially energetic particles like ions 51 00:02:54,020 --> 00:02:50,489 and electrons which come from Saturn 52 00:02:57,319 --> 00:02:54,030 because of its heavy because of its 53 00:02:59,949 --> 00:02:57,329 heavy magnetic field so there are some 54 00:03:02,119 --> 00:02:59,959 particles coming from Titans 55 00:03:05,030 --> 00:03:02,129 magnetosphere that's what we call and 56 00:03:08,180 --> 00:03:05,040 then these particles are going to be the 57 00:03:09,610 --> 00:03:08,190 second main influencer to start breaking 58 00:03:13,280 --> 00:03:09,620 these molecules and their chemistry 59 00:03:15,890 --> 00:03:13,290 starts so basically with these two main 60 00:03:18,759 --> 00:03:15,900 influences this remain Malik's are going 61 00:03:22,280 --> 00:03:18,769 to break and we're gonna start building 62 00:03:25,970 --> 00:03:22,290 more complex molecules from them so 63 00:03:28,970 --> 00:03:25,980 basically we have two main things called 64 00:03:33,559 --> 00:03:28,980 the dissociation and the ionization of 65 00:03:35,330 --> 00:03:33,569 these two molecules so this is the these 66 00:03:38,500 --> 00:03:35,340 are the two main processes that will 67 00:03:41,750 --> 00:03:38,510 create the the bigger molecules in Titan 68 00:03:45,280 --> 00:03:41,760 so just like the earth we can separate 69 00:03:48,949 --> 00:03:45,290 the the atmosphere in different layers 70 00:03:51,610 --> 00:03:48,959 but just to show you that here in the 71 00:03:57,259 --> 00:03:51,620 thermistors like the upper atmosphere 72 00:03:58,729 --> 00:03:57,269 about a thousand to 1400 um these are 73 00:04:01,819 --> 00:03:58,739 the two main models that I showed you 74 00:04:05,259 --> 00:04:01,829 methane and nitrogen so this area is 75 00:04:08,360 --> 00:04:05,269 where it out is where I'm going to start 76 00:04:10,819 --> 00:04:08,370 so when we go down the atmosphere we see 77 00:04:14,210 --> 00:04:10,829 the creation of more complex and organic 78 00:04:18,110 --> 00:04:14,220 molecules we can see here compounds made 79 00:04:21,199 --> 00:04:18,120 by carbon and hydrogen so when they're 80 00:04:23,990 --> 00:04:21,209 from they get heavier and then they go 81 00:04:26,190 --> 00:04:24,000 down the atmosphere so here in the 82 00:04:28,620 --> 00:04:26,200 lowest part this that 83 00:04:31,470 --> 00:04:28,630 the second lowest part dissatisfied we 84 00:04:34,320 --> 00:04:31,480 see something we call aerosol haze layer 85 00:04:36,930 --> 00:04:34,330 which are these organic molecules that 86 00:04:40,290 --> 00:04:36,940 start to condense and are gluten aid and 87 00:04:45,030 --> 00:04:40,300 if they form Isis and solid particles in 88 00:04:50,010 --> 00:04:45,040 the atmosphere so this which we call the 89 00:04:52,230 --> 00:04:50,020 haze layer is the reason we see when we 90 00:04:55,710 --> 00:04:52,240 observe Titan we see this very dense 91 00:04:57,810 --> 00:04:55,720 very thick kind of orange yellow 92 00:04:59,760 --> 00:04:57,820 atmosphere it's because of these 93 00:05:03,800 --> 00:04:59,770 particles these organic particles right 94 00:05:06,810 --> 00:05:03,810 here so I'm gonna talk now about my work 95 00:05:10,440 --> 00:05:06,820 this is me okay and these are my two 96 00:05:12,530 --> 00:05:10,450 advisors from from Brazil as well from 97 00:05:19,710 --> 00:05:12,540 the federal University of Rio de Janeiro 98 00:05:22,110 --> 00:05:19,720 so us three we got um we this is one of 99 00:05:24,750 --> 00:05:22,120 my advisors and she had this work with 100 00:05:28,620 --> 00:05:24,760 the southern offers where they developed 101 00:05:31,590 --> 00:05:28,630 a model to simulate atmosphere but not 102 00:05:35,300 --> 00:05:31,600 for Titan they develop it to study hot 103 00:05:38,100 --> 00:05:35,310 Jupiters so they're near my two advisors 104 00:05:41,580 --> 00:05:38,110 me a bunch of advisers we were like oh 105 00:05:43,140 --> 00:05:41,590 let's try this let's try this chemical 106 00:05:47,040 --> 00:05:43,150 model for something different for 107 00:05:49,680 --> 00:05:47,050 something that's more terrestrial maybe 108 00:05:52,110 --> 00:05:49,690 and which we know a little bit more 109 00:05:57,510 --> 00:05:52,120 because hot Jupiters are not really well 110 00:06:01,740 --> 00:05:57,520 known so we try this this chemical model 111 00:06:03,590 --> 00:06:01,750 for Titan but the problem was we can 112 00:06:06,000 --> 00:06:03,600 only work with the upper atmosphere 113 00:06:08,210 --> 00:06:06,010 that's not really a problem for us 114 00:06:11,790 --> 00:06:08,220 because as I showed you the main 115 00:06:14,970 --> 00:06:11,800 chemistry works a is really in the upper 116 00:06:18,350 --> 00:06:14,980 atmosphere in the thermosphere part but 117 00:06:22,370 --> 00:06:18,360 so basically this is why I studied 118 00:06:27,390 --> 00:06:22,380 Titans upper atmosphere so above a 119 00:06:30,540 --> 00:06:27,400 thousand kilometers and in the in the 120 00:06:33,360 --> 00:06:30,550 upper atmosphere we have these features 121 00:06:37,050 --> 00:06:33,370 is very important in my work which is 122 00:06:39,970 --> 00:06:37,060 called the atmospheric escape so some 123 00:06:42,330 --> 00:06:39,980 molecules are going to just 124 00:06:44,980 --> 00:06:42,340 escape the atmosphere as it happens here 125 00:06:48,940 --> 00:06:44,990 on the river as it happens in hot 126 00:06:52,290 --> 00:06:48,950 Jupiters and other atmospheres so this 127 00:06:55,720 --> 00:06:52,300 is how by this mechanism we're going to 128 00:07:00,100 --> 00:06:55,730 to analyze the formation of molecules in 129 00:07:03,280 --> 00:07:00,110 the atmosphere so um basically the first 130 00:07:05,050 --> 00:07:03,290 step of my work was we selected a bunch 131 00:07:07,060 --> 00:07:05,060 of species which we know from the 132 00:07:10,270 --> 00:07:07,070 literature that were in Titan's 133 00:07:12,700 --> 00:07:10,280 atmosphere so I went to a database 134 00:07:14,700 --> 00:07:12,710 called the you missed I don't know if 135 00:07:18,190 --> 00:07:14,710 any one who uses it 136 00:07:22,120 --> 00:07:18,200 it's database for interstellar molecules 137 00:07:26,500 --> 00:07:22,130 we had to adapt it to to put this 138 00:07:29,940 --> 00:07:26,510 molecules in Titan atmosphere and what 139 00:07:34,210 --> 00:07:29,950 after we selected this these compounds 140 00:07:36,430 --> 00:07:34,220 we here in the database we got all the 141 00:07:40,000 --> 00:07:36,440 reactions that these compounds go 142 00:07:42,550 --> 00:07:40,010 through so here for example this is a 143 00:07:47,590 --> 00:07:42,560 methane which is one of the main 144 00:07:49,450 --> 00:07:47,600 products of reactions in Titan so here 145 00:07:52,440 --> 00:07:49,460 in the database we have all the 146 00:07:55,090 --> 00:07:52,450 reactions that will happen with a thing 147 00:07:57,340 --> 00:07:55,100 for information and for destruction as 148 00:08:00,550 --> 00:07:57,350 well so we got all these reactions we 149 00:08:04,060 --> 00:08:00,560 got all day out there constants and we 150 00:08:06,670 --> 00:08:04,070 put it on the equations and this is um 151 00:08:09,640 --> 00:08:06,680 this is basically the word so the last 152 00:08:12,070 --> 00:08:09,650 part is we put all that reaction in 153 00:08:15,070 --> 00:08:12,080 equations in continuation continuity 154 00:08:18,490 --> 00:08:15,080 equations and we use the program to 155 00:08:20,800 --> 00:08:18,500 solve that so basically the continuity 156 00:08:23,560 --> 00:08:20,810 equation for the molecules is basically 157 00:08:25,870 --> 00:08:23,570 this one which is one molecule so we 158 00:08:28,870 --> 00:08:25,880 have one separate equation for each 159 00:08:32,110 --> 00:08:28,880 molecule we have like a 100 molecules or 160 00:08:34,690 --> 00:08:32,120 something so the reactions go right here 161 00:08:38,860 --> 00:08:34,700 this is a reactions product right and 162 00:08:42,190 --> 00:08:38,870 this is the loss rate but our um our 163 00:08:44,590 --> 00:08:42,200 mother our mother was um only 164 00:08:47,140 --> 00:08:44,600 dimensional and stationary so we didn't 165 00:08:51,630 --> 00:08:47,150 considered time so this goes to zero 166 00:08:54,030 --> 00:08:51,640 actually and then two to 167 00:08:57,410 --> 00:08:54,040 but this molecules in my work I had to 168 00:09:00,079 --> 00:08:57,420 put some previous profiles for the main 169 00:09:02,699 --> 00:09:00,089 molecules so I put the profiles for 170 00:09:06,210 --> 00:09:02,709 nitrogen and for methane 171 00:09:08,670 --> 00:09:06,220 I also use the profile for hydrogen 172 00:09:11,009 --> 00:09:08,680 molecular hydrogen because it's the main 173 00:09:12,990 --> 00:09:11,019 molecule that's going to escape the 174 00:09:14,100 --> 00:09:13,000 atmosphere and sit for working with 175 00:09:17,730 --> 00:09:14,110 upper atmosphere 176 00:09:22,590 --> 00:09:17,740 I used hydrogen as well these two 177 00:09:24,720 --> 00:09:22,600 profiles are from this work in 2008 so 178 00:09:27,780 --> 00:09:24,730 this is our result I'm gonna show you 179 00:09:29,449 --> 00:09:27,790 the main marks we found basically these 180 00:09:33,449 --> 00:09:29,459 three main molecules which are called 181 00:09:37,019 --> 00:09:33,459 acetylene ethylene anything are the 182 00:09:39,150 --> 00:09:37,029 three main products my reactions in 183 00:09:42,060 --> 00:09:39,160 Titan's atmosphere so this is their 184 00:09:45,180 --> 00:09:42,070 abundances and this is the altitude it's 185 00:09:48,750 --> 00:09:45,190 in the horizontal but you pretend like 186 00:09:50,850 --> 00:09:48,760 the Titan is here and the altitude is 187 00:09:53,730 --> 00:09:50,860 going that way so these are the three 188 00:09:57,530 --> 00:09:53,740 and this remaining molecules we found by 189 00:09:59,720 --> 00:09:57,540 that products by that reaction sorry and 190 00:10:02,750 --> 00:09:59,730 these are basically the hyper 191 00:10:07,139 --> 00:10:02,760 hydrocarbon molecules so we also find 192 00:10:09,560 --> 00:10:07,149 molecules with oxygen but I didn't 193 00:10:12,780 --> 00:10:09,570 mention oxygen before because it's not 194 00:10:16,319 --> 00:10:12,790 it's initially not in Titan's atmosphere 195 00:10:19,860 --> 00:10:16,329 it actually comes from Enceladus so it 196 00:10:22,769 --> 00:10:19,870 has a inflow of oxygen especially 197 00:10:26,759 --> 00:10:22,779 especially oxygen ions in the atmosphere 198 00:10:31,040 --> 00:10:26,769 so we also we can also see some some 199 00:10:35,579 --> 00:10:31,050 oxygen bearing molecules here and we see 200 00:10:38,579 --> 00:10:35,589 co which is basically um I guess the 201 00:10:41,759 --> 00:10:38,589 fourth may molecule in in the atmosphere 202 00:10:43,949 --> 00:10:41,769 and it's really stable because its 203 00:10:46,170 --> 00:10:43,959 contents temperature is really cold so 204 00:10:49,110 --> 00:10:46,180 it basically doesn't condense in fact in 205 00:10:51,840 --> 00:10:49,120 the atmosphere and the best part for me 206 00:10:53,699 --> 00:10:51,850 is that we also found nitrogen bearing 207 00:10:56,550 --> 00:10:53,709 molecules which is important for life 208 00:10:58,620 --> 00:10:56,560 and stuff so this is the main molecule 209 00:11:01,199 --> 00:10:58,630 we found which is hydrogen cyanide is 210 00:11:04,830 --> 00:11:01,209 one of the basic molecules we can find 211 00:11:08,310 --> 00:11:04,840 in the interstellar medium and we're 212 00:11:11,250 --> 00:11:08,320 found different molecules as well so we 213 00:11:13,620 --> 00:11:11,260 found some we found some complex 214 00:11:15,930 --> 00:11:13,630 molecules which is great for us because 215 00:11:18,870 --> 00:11:15,940 you can see this like anywhere else in 216 00:11:21,420 --> 00:11:18,880 the solar system so we found this one 217 00:11:25,530 --> 00:11:21,430 for examples for pure nitrile we found 218 00:11:29,400 --> 00:11:25,540 Osetra nitrile and this CN was settling 219 00:11:32,880 --> 00:11:29,410 to me and yes that's a pretty great 220 00:11:35,460 --> 00:11:32,890 result for us um another thing we did in 221 00:11:37,500 --> 00:11:35,470 our work was try to show the difference 222 00:11:39,510 --> 00:11:37,510 between considering the energetic 223 00:11:42,570 --> 00:11:39,520 particles that come from Saturn's 224 00:11:45,380 --> 00:11:42,580 magnetosphere so we tried to run the 225 00:11:50,870 --> 00:11:45,390 model with and without this influence of 226 00:11:54,330 --> 00:11:50,880 energetic particles so I show you here 227 00:11:57,960 --> 00:11:54,340 some molecules and some ions and we can 228 00:12:00,750 --> 00:11:57,970 see if um these these direct ones are 229 00:12:03,200 --> 00:12:00,760 without the magnetospheric influence and 230 00:12:06,590 --> 00:12:03,210 the solid ones are considering the 231 00:12:09,690 --> 00:12:06,600 magnetospheric influence so we basically 232 00:12:12,540 --> 00:12:09,700 discovered that this influence is 233 00:12:15,090 --> 00:12:12,550 especially in small molecules and ions 234 00:12:18,590 --> 00:12:15,100 so the biggest molecules we found they 235 00:12:22,260 --> 00:12:18,600 were not affected by this this 236 00:12:24,810 --> 00:12:22,270 magnetospheric energetic particles so 237 00:12:25,440 --> 00:12:24,820 basically this comes this concludes my 238 00:12:29,640 --> 00:12:25,450 work 239 00:12:33,000 --> 00:12:29,650 we found the abundances the simulated 240 00:12:37,950 --> 00:12:33,010 abundances for compounds with carbon 241 00:12:40,890 --> 00:12:37,960 hydrogen oxygen and nitrogen we got um a 242 00:12:44,370 --> 00:12:40,900 pretty good simulation considering we 243 00:12:46,860 --> 00:12:44,380 didn't consider other mechanisms like 244 00:12:48,900 --> 00:12:46,870 the haze formation which is lower in the 245 00:12:51,650 --> 00:12:48,910 atmosphere we just consider the upper 246 00:12:54,960 --> 00:12:51,660 atmosphere for this work and we also 247 00:12:58,680 --> 00:12:54,970 found some visible effects of the 248 00:13:01,470 --> 00:12:58,690 influence of Saturn's magnetosphere so 249 00:13:03,900 --> 00:13:01,480 for the future what I want to do with 250 00:13:06,060 --> 00:13:03,910 this work maybe not me but some other 251 00:13:09,900 --> 00:13:06,070 student we want to try to include more 252 00:13:12,360 --> 00:13:09,910 molecules in this model especially maybe 253 00:13:14,700 --> 00:13:12,370 sulfur and phosphorus molecules which 254 00:13:18,720 --> 00:13:14,710 are also really important if we want to 255 00:13:22,890 --> 00:13:18,730 find life somewhere we want to include 256 00:13:25,890 --> 00:13:22,900 the Collins and his formations so we 257 00:13:27,480 --> 00:13:25,900 want to to run the model for all the 258 00:13:31,410 --> 00:13:27,490 atmosphere not just the upper atmosphere 259 00:13:33,560 --> 00:13:31,420 and we want to try to do some lab 260 00:13:36,390 --> 00:13:33,570 experiments trying to simulate that 261 00:13:39,390 --> 00:13:36,400 really in a chamber with all the 262 00:13:41,130 --> 00:13:39,400 molecules we found and see if that could 263 00:13:44,850 --> 00:13:41,140 develop anything else or anything 264 00:13:49,280 --> 00:13:44,860 different we from we found in the 265 00:13:53,490 --> 00:13:49,290 computer in the computer computer model 266 00:13:55,650 --> 00:13:53,500 this is basically my wor solo I'm open 267 00:14:06,890 --> 00:13:55,660 to any questions now if you have them 268 00:14:09,540 --> 00:14:06,900 thank you thank you very much for that 269 00:14:10,710 --> 00:14:09,550 thank you very much for the talk we have 270 00:14:21,560 --> 00:14:10,720 any questions we got time for maybe one 271 00:14:24,840 --> 00:14:21,570 or two so the question is about 272 00:14:32,700 --> 00:14:24,850 methodology from your ears to your 273 00:14:36,150 --> 00:14:32,710 modeling okay so we when we had to put 274 00:14:39,450 --> 00:14:36,160 each reaction in this continuous 275 00:14:43,430 --> 00:14:39,460 irritation equation we have for example 276 00:14:48,890 --> 00:14:43,440 from the database we have the reactions 277 00:14:52,080 --> 00:14:48,900 constants constants and then we put on 278 00:14:57,900 --> 00:14:52,090 we put on this continuity equation but 279 00:15:02,280 --> 00:14:57,910 we adhere factor to to consider the 280 00:15:04,560 --> 00:15:02,290 folks from system and the flux from the 281 00:15:06,930 --> 00:15:04,570 energetic particles no sorry it's 282 00:15:10,230 --> 00:15:06,940 actually here so we have here the flux 283 00:15:14,910 --> 00:15:10,240 factor then we add another constant here 284 00:15:19,470 --> 00:15:14,920 to to consider this influence so we did 285 00:15:22,380 --> 00:15:19,480 that for two different things for the UV 286 00:15:26,280 --> 00:15:22,390 sunlight and then for the Saturn 287 00:15:28,590 --> 00:15:26,290 energetic particles I just um I went 288 00:15:41,370 --> 00:15:28,600 through this part because it's it's the 289 00:15:41,380 --> 00:15:51,830 [Music] 290 00:16:04,500 --> 00:16:01,800 with it with it we actually um yes we're 291 00:16:06,960 --> 00:16:04,510 considered elected to it all uniform but 292 00:16:11,190 --> 00:16:06,970 we actually know in fact that Murphy we 293 00:16:13,530 --> 00:16:11,200 have wind and circulation of convection 294 00:16:15,780 --> 00:16:13,540 circulation this is something else we 295 00:16:39,210 --> 00:16:15,790 could put in the model but it's a really 296 00:16:42,900 --> 00:16:39,220 difficult thing to do so since we did 297 00:16:45,380 --> 00:16:42,910 consider but is here in the upper 298 00:16:52,940 --> 00:16:45,390 atmosphere they're not really in 299 00:17:02,010 --> 00:16:54,800 like 300 00:17:10,290 --> 00:17:05,130 yeah we considered they're all going to 301 00:17:14,010 --> 00:17:10,300 - they're going to be uniform basically 302 00:17:16,189 --> 00:17:14,020 as I said in the latitude and everywhere 303 00:17:20,429 --> 00:17:16,199 else but we just considered a 304 00:17:22,010 --> 00:17:20,439 one-dimensional model so this is we 305 00:17:25,020 --> 00:17:22,020 actually work with the altitude 306 00:17:27,929 --> 00:17:25,030 dimension I'm sorry to put it in the 307 00:17:30,090 --> 00:17:27,939 horizontally this is not very this is 308 00:17:32,910 --> 00:17:30,100 very weird for me but the model works 309 00:17:34,890 --> 00:17:32,920 like this so we only considered this 310 00:17:36,330 --> 00:17:34,900 direction the other directions were not